Urea Activation by an External Brønsted Acid: Breaking Self-Association and Tuning Catalytic Performance Isaac G. Sonsona, Eugenia Marqués-López, Marleen Häring, David Díaz Díaz and Raquel P. Herrera Catalysts 2018, 8(8), 305; https://doi.org/10.3390/catal8080305 Abstract: In this work, we hypothesize that Brønsted acids can activate urea-based catalysts by diminishing its … Continue reading
Last wednesday, Sandra presented her Bachelor thesis entitled “Synthesis and applications of heterocycles of interest”. She did it excellent. Congratulations!
Juanvi has been in Arantzazu (Gipuzkoa), from October 16th to 19th working with other PhD students in the “Doctoriales transfronterizos UPPA-UPV/EHU” (UPPA-UPV / EHU Transboundary Doctorials), organized by the Master’s and Doctorate School of the UPV / EHU (MDe), in collaboration with the … Continue reading
Juanvi has worked hard in this project and now the first results have just come out. The central idea is to generate in situ, the carbonyl compound, via oxidation of an alcohol, which is involved in a subsequent asymmetric organocatalytic … Continue reading
We have just published very interesting studies about the Henry reaction, which allow understanding more in detail the activation of the substrates by a very effective squaramide. Enjoy them… Congratulations Juanvi! “Push−Pull π+/π−” (PPππ) Systems in Catalysis, Alegre Requena J. … Continue reading
Asymmetric Organocatalytic Synthesis of Substituted Chiral 1,4-Dihydropyridine Derivatives. Fernando Auria-Luna, Eugenia Marqués-López, M. Concepción Gimeno, Roghayeh Heiran, Somayeh Mohammadi, and Raquel P. Herrera, J. Org. Chem. 2017, 82, 5516–5523. Abstract. The first cinchona-alkaloid-organocatalyzed enantioselective synthesis of chiral 1,4-dihydropyridine derivatives is described. Bis-cinchona catalyst 3b … Continue reading
Organocatalytic enantioselective synthesis of 1,4-dihydropyridines, Auria-Luna, F.; Marqués-López, E.; Herrera, R. P. Adv. Synth. Catal. 2017, DOI 10.1002/adsc.201700300 Abstract. This review aims to bring light upon a very interesting group of compounds, the 1,4-dihydropyridines (1,4-DHPs). These structures are well-known pharmacophores, used for many years … Continue reading
Organocatalytic Hydrophosphonylation Reaction of Carbonyl Groups. Herrera, R. P. Chem. Rec. 2017, DOI: 10.1002/tcr.201600129. Abstract. This revision is covering the limited examples reported for a pivotal strategy in the formation of C−P bonds such as the asymmetric organocatalytic hydrophosphonylation of carbonyl groups … Continue reading
Juanvi, has recently attended to the 8th European Symposium on Computing π-Conjugated Compounds, celebrated in Malaga from Jan. 27th to 28th. There, he presented an oral communication about the most recent results of his doctoral thesis in the field of … Continue reading
A new article has just been accepted. Congratulations! Gold(I) mediated thiourea organocatalyst activation: A synergic effect for asymmetric catalysis. Anabel Izaga, Raquel P. Herrera, M. Concepción Gimeno, ChemCatChem, 2017, 10.1002/cctc.201601527. Abstract. Several group 11 metal complexes with chiral thiourea organocatalysts have … Continue reading
