Recent publications

2010-present

78.- Simple iodoalkyne-based organocatalysts for the activation of carbonyl compounds, Alegre-Requena, J. V.; Valero-Tena, A.; Sonsona, I. G.; Uriel, S.; Herrera, R. P. Org. Biomol. Chem. 2020, 18, 1594-1601. https://doi.org/10.1039/C9OB02688F

77.- Functionalization of π-activated alcohols by trapping carbocations in pure water under smooth conditions, Ortiz, R.; Koukouras, A.; Marqués-López, E.; Herrera, R. P. Arab. J. Chem. 2020, 13, 18661873. https://doi.org/10.1016/j.arabjc.2018.01.022

76.- Hydrogen bonding and Internal or External Lewis or Brønsted Acid Assisted (Thio)urea Catalysts, Gimeno, M. C.; Herrera, R. P. Eur. J. Org. Chem. 2020, 10571068. https://doi.org/10.1002/ejoc.201901344

75.- Synthesis, structural determination and catalytic study of a new 2-D chloro-substituted zinc phosphate, (C8N2H20)[ZnCl(PO3(OH))]2, Rayes, A.; Herrera, R. P.; Moncer, M.; Ara, I.; Calestani, G.; Ayed, B.; Mezzadri, F. J. Mol. Struct. 2020, 1202, 127216, https://doi.org/10.1016/j.molstruc.2019.127216

74.- Thiolate Bridged Gold(I) NHC Catalysts: New Approach for Catalyst Design and its Application Trapping Catalytic Intermediates, Visbal, R.; Herrera, R. P.; Gimeno, M. C. Chem. Eur. J. 2019, 25, 1583715845. https://doi.org/10.1002/chem.201903494. HOT PAPER

73.- First aromatic amine organocatalysed activation of α,β-unsaturated ketones,  Sonsona, I. G.; Marqués-López, E.; Gimeno, M. C.; Herrera, R. P. New J. Chem. 2019, 43, 1223312240. DOI: 10.1039/c9nj02392e.

72.- Proline bulky substituents consecutively act as steric hindrances and directing groups in a Michael/Conia-ene cascade reaction under synergistic catalysis, Putatunda, S.; Alegre-Requena, J. V.; Meazza, M.; Franc, M.; Rohaľová, D.; Vemuri, P.; Císařová, I.; Herrera, R. P.; Rios, R.; Veselý, J. Chem. Sci. 2019, 10, 4107–4115. DOI: 10.1039/C8SC05258A This paper has been selected as one of the best organocatalytic papers published in Chemical Science to celebrate the Nobel Prize in Organocatalysis

71.- Bioactive and luminescent indole and isatin based gold(I) derivatives, Fernández-Moreira, V.; Val-Campillo, C.; Ospino, I.; Herrera, R. P.; Marzo, I.; Laguna, A.; Gimeno, M. C. Dalton Trans. 2019, 48, 3098-3108. DOI: 10.1039/C8DT00298C

70.- Anticancer Properties of Gold Complexes with Biologically Relevant Ligands, Fernández-Moreira, V.; Herrera, R. P.; Gimeno, M. C. Pure Appl. Chem. 2019, 91, 247–269. DOI: https://doi.org/10.1515/pac-2018-0901

69.- First Organocatalytic Asymmetric Synthesis of 1-Benzamido-1,4-Dihydropyridine Derivatives,  Auria-Luna, F.; Marqués-López, E.; Herrera, R. P.  Molecules 2018, 23(10), 2692. https://doi.org/10.3390/molecules23102692. Special Issue “Stereogenic Centers”

68.- Gold Catalyzed Multicomponent Reactions beyond A3Coupling, Visbal, R.; Graus, S.; Herrera, R. P.; GimenoM. C. Molecules 201823(9), 2255. https://doi.org/10.3390/molecules23092255

67.- Efficient Gold(I) Acyclic Diaminocarbenes for the Synthesis of Propargylamines and Indolizines, Aliaga-Lavrijsen, M.; Herrera, R. P.; Villacampa, M- D.; Gimeno, M. C. ACS Omega 20183, 9805–9813. DOI:10.1021/acsomega.8b01352

66.- Urea Activation by an External Brønsted Acid: Breaking Self-Association and Tuning Catalytic PerformanceSonsona, I. G.; Marqués-López, E.; Häring, M.; Díaz Díaz, D.; Herrera, R. P. Catalysts 20188, 305. https://doi.org/10.3390/catal8080305

65.- Synthesis and supramolecular self-assembly of glutamic acid-based squaramides, Alegre-Requena, J. V.;  Häring, M.; Sonsona, S. G.; Abramov, A.; Marqués-López, E.; Herrera, R. P.; Díaz Díaz, D. Beilstein J. Org. Chem. 2018, 14, 2065–2073. doi:10.3762/bjoc.14.180

64.- Hydrothermal synthesis of CoII chiral inorganic-organic complex: Structural, thermal and catalytic evaluation, Maatar Ben Salah, A.; Herrera, R. P.; Naïli, H. J. Mol. Struct. 2018, 1165, 356–362. https://doi.org/10.1016/j.molstruc.2018.04.002

63.- Synthesis, structural determination and antimicrobial evaluation of two novel CoII and ZnII halogenometallates as efficient catalysts for the acetalization reaction of aldehydes, Maatar Ben Salah, A.; Belghith Fendri, L.; Bataille, T.; Herrera, R. P.; Naïli, H. Chem. Cent. J. 2018, 12:24. https://doi.org/10.1186/s13065-018-0393-6

62.- Organocatalyzed enantioselective aldol and Henry reactions
starting from benzylic alcohols, Alegre Requena J. V.; Marqués-López, E.; Herrera, R. P. Adv. Synth. Catal. 2018360, 124–129. https://doi.org/10.1002/adsc.201701351

61.- Highly active group 11 metal complexes with α-hydrazidophosphonate ligands Dalton Trans. 2017, 46, 13745–13755.

60.- Optimizing Accuracy and Computational Cost in Theoretical Squaramide Catalysis: the Henry Reaction, Alegre Requena J. V.; Marqués-López, E.; Herrera, R. P. Chem. Eur. J. 201723, 15336–15347. HOT PAPER. Frontispiece under invitation.

59.- “Push−Pull π+/π−” (PPππ) Systems in Catalysis, Alegre Requena J. V.; Marqués-López, E.; Herrera, R. P. ACS Catal. 2017, 7, 6430–6439. https://doi.org/10.1021/acscatal.7b02446. Cover under invitation.

58.- Asymmetric Organocatalytic Synthesis of Substituted Chiral 1,4-Dihydropyridine DerivativesAuria-Luna, F.; Marqués-López, E.; Gimeno, M. C.; Heiran, R.; Mohammadi, S.; Herrera, R. P. J. Org. Chem. 2017, 82, 5516–5523. https://doi.org/10.1021/acs.joc.7b00176.

57.- Organocatalytic enantioselective synthesis of 1,4-dihydropyridines, Auria-Luna, F.; Marqués-López, E.; Herrera, R. P.  Adv. Synth. Catal. 2017, 359, 2161–2175. https://doi.org/10.1002/adsc.201700300.

56.- Direct Substitution of Alcohols in Pure Water by Brønsted Acid Catalysis, Ortiz, R.; Herrera, R. P. Molecules 2017, 22(4), 574; DOI:10.3390/molecules22040574.

55.- Organocatalytic Hydrophosphonylation Reaction of Carbonyl Groups. Herrera, R. P. Chem. Rec. 2017, 17, 833–840.

54.- Gold(I) mediated thiourea organocatalyst activation: A synergic effect for asymmetric catalysis. Izaga, A.; Herrera, R. P.; Gimeno, M. C. ChemCatChem 2017, 9,  1313–1321.

53.- Synergistic Catalysis: Asymmetric Synthesis of Cyclopentanes Bearing Four Stereogenic Centers. Zhang, K.; Meazza, M.; Izaga, A.; Contamine, C.; Gimeno, M. C.; Herrera, R. P.; Rios, R. Synthesis 2017, 49, 167–174.

52.- One-Pot Synthesis of Squaramides. Alegre-Requena, J. V.; Marqués-López, E.; Herrera, R. P. PCT Int. Appl. 2016, WO 2016005407 A1 20160114.

51.- Hydrogen bonding networks in chiral thiourea organocatalysts. Evidence on the importance of the aminoindanol moiety. Gimeno, M. C.; Herrera, R. P. Cryst. Growth Des. 2016, 16, 5091–5099.

50.- Regulatory Parameters of Self-Healing Alginate Hydrogel Networks Prepared via Mussel-Inspired Dynamic Chemistry. Alegre-Requena, J. V.; Haering, M.; Herrera, R. P.; Diaz Diaz, D. New J. Chem. 2016, 40, 8493–8501.

49.- Crystallisation, thermal analysis and acetal protection activity of new layered Zn(II) hybrid polymorphs. Saïd, S.; Naïli, H.; Bataille, T.; Herrera, R. P. CrystEngComm 2016, 18, 5365–5374.

48.- Organocatalytic Transfer Hydrogenation and Hydrosilylation Reactions. Herrera, R. P. Top. Curr. Chem. 2016, 374, 29. DOI: 10.1007/s41061-016-0032-4. This article is part of the Topical CollectionHydrogen Transfer Reactions”; edited by Gabriela Guillena, Diego J. Ramón.

47.- Fluoride anion recognition by a multifunctional urea derivative: An experimental and theoretical study. Schiller, J.; Pérez-Ruiz, R.; Sampedro, D.; Marqués-López, E.; Herrera, R. P.; Diaz Diaz, D. Sensors 2016, 16(5), 658. DOI: 10.3390/s16050658. Special Issue “Colorimetric and Fluorescent Sensor

46.- Trifunctional squaramide catalyst for efficient enantioselective Henry reaction activation. Alegre-Requena, J. V.; Marqués-López, E.; Herrera, R. P. Adv. Synth. Catal. 2016, 358, 1801–1809. https://doi.org/10.1002/adsc.201600046. Highlighted in Synfacts 2016, 12, 743.

45.- Self-assembled fibrillar networks of a multifaceted chiral squaramide: supramolecular multistimuli-responsive alcogels. Schiller, J.; Alegre-Requena, J. V.; Marqués-López, E.; Herrera, R. P.; Casanovas, J.; Alemán, C.; Diaz Diaz, D. Soft Matter 2016, 12, 4361–4374.

44.- The aminoindanol core as a key scaffold in bifunctional organocatalysts. Sonsona, I. G.; Marqués-López, E.; Herrera, R. P. Beilstein J. Org. Chem. 2016, 12, 505–523.

43.- Squaramides with cytotoxic activity against human gastric carcinoma cells HGC-27: synthesis and mechanism of action. Quintana, M.; Alegre-Requena, J. V.; Marqués-López, E.; Herrera, R. P.; Triola, G. Med. Chem. Commun. 2016, 7, 550–561Special issue “New Talents: Europe. Medicinal Chemistry”

42.- Synthesis of Luminescent Squaramide Monoesters: Cytotoxicity and Cell Imaging Studies in HeLa Cells. Fernandez-Moreira, V.; Alegre-Requena, J. V.; Herrera, R. P.; Marzo, I.; Gimeno, M. C. RSC Adv. 2016, 6, 14171–14177.

41.- Metal-organic Frameworks (MOFs) Bring New Life to Hydrogen-bonding Organocatalysts in Confined SpacesAlegre-Requena, J. V.; Marqués-López, E.; Herrera R. P.; Diaz Diaz, D. CrystEngComm 2016, 18, 3985–3995Special issue “New Talent

40.- New Organocatalytic Asymmetric Synthesis of Highly Substituted Chiral 2-Oxo Spiro-[indole-3,4′-(1′,4′-dihydropyridine)] DerivativesAuria-Luna, F.; Marqués-López, E.; Mohammadi, S.; Heiran, R.; Herrera, R. P. Molecules 2015, 20, 15807–15826. Special issue “Organocatalysis 2015”

39.- Enantioselective Organocatalyzed Synthesis of 2-Amino-3-cyano-4H-chromene Derivatives. Sonsona, I. G.; Marqués-López, E.; Herrera, R. P. Symmetry 2015, 7, 1519–1535. Special issue “Asymmetric Organocatalysis”

38.- Indole, a Privileged Structural Core Motif. Sonsona, I. G. Synlett, 2015, 26, 2325–2326.

37.- Thiourea-Catalyzed Addition of Indoles to Aliphatic β,γ-Unsaturated α-Ketoesters. Juste-Navarro, V.; Marqués-López, E.; Herrera, R. P. Asian J. Org. Chem. 2015, 4, 884–889.

36.- One-Pot Synthesis of Unsymmetrical Squaramides. Alegre-Requena, J. V.; Marqués-López, E.; Herrera, R. P. RSC Adv. 2015, 5, 33450–33462.

35.- Marqués-López, E.; Herrera, R. P. Essential Multicomponent Reactions I in Multicomponent Reactions. Concepts and Applications for Design and Synthesis. (Eds. Herrera, R. P. and Marqués-López, E.) Wiley-VCH; 2015, 382–415. ISBN: 978-1-118-01600-8.

34.- Marqués-López, E.; Herrera, R. P.; Rios, R. Unusual Approach for Multicomponent Reactions in Multicomponent Reactions. Concepts and Applications for Design and Synthesis. (Eds. Herrera, R. P. and Marqués-López, E.) Wiley-VCH; 2015, 358–381. ISBN: 978-1-118-01600-8.

33.Marqués-López, E.; Herrera, R. P. Bucherer-Bergs and Strecker Multicomponent Reactions in Multicomponent Reactions. Concepts and Applications for Design and Synthesis. (Eds. Herrera, R. P. and Marqués-López, E.) Wiley-VCH; 2015, 331–357. ISBN: 978-1-118-01600-8.

32. Marqués-López, E.; Herrera, R. P. Biginelli Multicomponent Reactions in Multicomponent Reactions. Concepts and Applications for Design and Synthesis. (Eds. Herrera, R. P. and Marqués-López, E.) Wiley-VCH; 2015, 306–330. ISBN: 978-1-118-01600-8.

31.- Marqués-López, E. y Herrera, R. P. Passerini Multicomponent Reactions in Multicomponent Reactions. Concepts and Applications for Design and Synthesis. (Eds. Herrera, R. P. and Marqués-López, E.) Wiley-VCH; 2015, 283–305. ISBN: 978-1-118-01600-8.

30. Marqués-López, E.; Herrera, R. P.; Radtke, L. Multicomponent Reactions in the Synthesis of Target Molecules in Multicomponent Reactions. Concepts and Applications for Design and Synthesis. (Eds. Herrera, R. P. and Marqués-López, E.) Wiley-VCH; 2015, 198-246. ISBN: 978-1-118-01600-8.

29. Marqués-López, E.; Herrera, R. P. Multicomponent Reactions with Organoboron Compounds in Multicomponent Reactions. Concepts and Applications for Design and Synthesis. (Eds. Herrera, R. P. and Marqués-López, E.) Wiley-VCH; 2015, 127–148. ISBN: 978-1-118-01600-8.

28. Alegre-Requena, J. V.; Marqués-López, E.; Herrera, R. P. Introduction to the Multicomponent Reactions in Multicomponent Reactions. Concepts and Applications for Design and Synthesis. (Eds. Herrera, R. P. and Marqués-López, E.) Wiley-VCH; 2015, 1–15. ISBN: 978-1-118-01600-8.

27. Fluxional Amine Gold(III) Complex as Excellent Catalyst and Precursor of Biologically Active Acyclic Carbenes. Montanel‐Pérez, S.; Herrera, R. P.; Laguna, A.; Villacampa, M. D.; Gimeno, M. C. Dalton Trans. 2015, 44, 9052–9062.

26.Marqués-López, E.; Herrera, R. P. Thiourea-Catalyzed Formation of Heterocyclic Compounds in Targets in Heterocyclic Systems – Chemistry and Properties. (Ed. Attanasi, O. A.) Società Chimica Italiana, 2014, Vol. 18. pp. 236–261. ISBN 978-88-86208-98-7.

25.- Squaramides, Discovering a New Crucial Scaffold. Alegre-Requena, J. V. Synlett 2014, 298–299.

24. A New Approach for the Synthesis of Bisindoles through AgOTf as Catalyst. Beltrá, J.; Gimeno, M. C.; Herrera, R. P. Beilstein J. Org. Chem. 2014, 10, 2206–2214.

23. Exploiting Molecular Self-Assembly: From Urea-Based Organocatalysts to Multifunctional Supramolecular Gels. Schön, E.-M.; Marqués-López, E.; Herrera, R. P.; Alemán, C.; Diaz Diaz, D. Chem. Eur. J. 2014, 20, 10720–10731. Special issue “European Young Chemists”

22. A Friedel-Crafts Alkylation Mechanism using Aminoindanol Derived Thiourea Catalyst. Roca-López, D.; Marqués-López, E.; Alcaine, A.; Merino, P.; Herrera, R. P. Org. Biomol. Chem. 2014, 12, 4503–4510.

21. Guanidine Motif in Biologically Active Peptides. Alegre-Requena, J. V.; Marqués-López, E.; Herrera, R. P. Aust. J. Chem. 2014, 67, 965–971. Special issue “Guanidine Chemistry”

20. Organocatalytic Enantioselective Hydrophosphonylation of Aldehydes. Alegre-Requena, J. V.; Marqués-López, E.; Miguel, P. J. S.; Herrera, R. P. Org. Biomol. Chem. 2014, 12, 1258–1264.

19. Synthesis of Interesting β-Nitrohydrazides through Thiourea Organocatalyzed aza-Michael Addition. Alcaine, A.; Marqués-López, E.; Herrera, R. P. RSC Adv. 2014, 4, 9856–9865.

18.- Asymmetric Organocatalytic Strecker-type Reactions of Aliphatic N,N-Dialkylhydrazones. A. Martínez-Muñoz, D. Monge, E. Martín-Zamora, E. Marqués-López, E. Álvarez, R. Fernández, J. M. Lassaletta. Org. Biomol. Chem. 2013, 11, 8247–8255.

17.. Marqués-López, E.; Herrera, R. P. Asymmetric Organocatalysis in Total Synthesis in Comprehensive Enantioselective Organocatalysis (Ed. Dalko, P.) Wiley-VCH; 2013, 1359–1383. ISBN: 978-3-527-33236-6.

16. Enantioselective Rauhut-Currier-Type Cyclizations via Dienamine Activation: Scope and Mechanism. Marqués-López, E.; Herrera, R. P.; Marks, T.; Jacobs, W. C.; Christmann, M. Synthesis 2013, 1016–1028. (Feature Article).

15. Isatin as a Strategic Motif for Asymmetric Catalysis. Mohammadi, S.; Heiran, R.; Herrera, R. P.; Marqués-López, E. ChemCatChem 2013, 5, 2131–2148.

14.- β-Lactones through Catalytic Asymmetric Heterodimerization of Ketenes. E. Marqués-López, M. Christmann. Angew. Chem. Int. Ed. 2012, 51, 8696–8698.

13.- Studies on the Synthesis of 2-Alkyl-5-aryl-1,3,4-Oxadiazolines from N-Acylhydrazones. E. Marqués-López, E. Díez, E. Martín-Zamora, E. Álvarez, R. Fernández, J. M. Lassaletta. Synlett 2012, 885–888.

12. Marqués-López, E. Herrera, R. P. Hydrogen Bonds as an Alternative Activation in New Strategies in Chemical Synthesis and Catalysis. (Ed. Pignataro, B.) John Wiley & sons; 2012 175–199. ISBN: 978-3-527-33090-4.

11.- Enhanced Efficiency of Thiourea Catalysts by External Brønsted Acids in the Friedel-Crafts Alkylation of Indoles. Marqués-López, E.; Alcaine, A.; Tejero, T.; Herrera, R. P. Eur. J. Org. Chem. 2011, 3700–3705. Special issueWoman in Chemistry IYC 2011

10. Organocatalytic Enantioselective Henry Reactions. Alvarez-Casao, Y.; Marqués-López, E.; Herrera, R. P. Symmetry 2011, 3, 220–245. Special issueAsymmetric Organocatalysis”. One of the most cited papers in Symmetry

9. Organocatalyzed Michael Addition Reaction by Novel (2R,3aS,7aS)-octa-hydroindole-2-carboxylic Acid, a New Fused Proline. Roca-Lopez, D.; Merino, P.; Sayago, F. J.; Cativiela, C.; Herrera, R. P. Synlett 2011, 249–253.

8.- Enantioselective α- and γ-Alkylation of α,β-Unsaturated Aldehydes using Dienamine Activation. Stiller, J.; Marqués-López E.; Herrera, R. P.; Fröhlich, R.; Strohmann, C.; Christmann M. Org. Lett. 2011, 13, 70–73.

7. Thiourea Catalyzed Organocatalytic Enantioselective Michael Addition of Diphenyl Phosphite to Nitroalkenes. Alcaine, A.; Marqués-López, E.; Merino, P.; Tejero, T.; Herrera, R. P. Org. Biomol. Chem. 2011, 9, 2777–2783.

6. Diarylprolinol Derivatives in Organocatalysis under Other Point of View: Structural Aspects. Marqués-López, E.; Herrera, R. P. Curr. Org. Chem. 2011, 15, 2311–2327. Herrera, R. P. guest editor of special issue:Fundamentals in Organocatalysis. Past, Present and Future.

5.- Silyl-Modified Analogues of 2-Tritylpyrrolidine: Synthesis and Applications in Asymmetric Organocatalysis. J. O. Bauer, J. Stiller, E. Marqués-López, K. Strohfeldt, M. Christmann, C. Strohmann. Chem.–Eur. J. 2010, 16, 12553–12558.

4. Asymmetric Organocatalytic Synthesis of γ-Nitrocarbonyl Compounds through Michael and Domino Reactions. Roca-Lopez, D.; Sadaba, D.; Delso, I.; Herrera, R. P.; Tejero, T.; Merino, P. Tetrahedron: Asymmetry 2010, 21, 2561–2601.

3.- Asymmetric Organocatalysis in Total Synthesis – A Trial by Fire. Marqués-López, E.; Herrera, R. P.; Christmann, M. Nat. Prod. Rep. 2010, 27, 1138–1167.

From September / October 2017, this much-cited article received enough cites to be included in the 1% of the best articles of the Academic area of Pharmacology & Toxicology based on a threshold of articles very cited for the area and the year of publication. (Data of Essential Science Indicators).

2. Uncatalyzed Three-component Synthesis of α-Hydrazido Phosphonates. Herrera, R. P.; Roca-López, D.; Navarro-Moros, G. Eur. J. Org. Chem. 2010, 1450–1454.

1. Enantioselective Organocatalytic Diels-Alder Reactions. Merino, P.; Marqués-López, E.; Tejero, T.; Herrera, R. P. Synthesis 2010, 1–26.

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